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A Novel Class of PN3 Pincer Ligands for Metal-Ligand Cooperative Catalysis

Topic:A Novel Class of PN3 Pincer Ligands for Metal-Ligand Cooperative Catalysis

Lecturer:Dr. Kuo-Wei Huang

KAUST Catalysis Center and Division of Physical Science and Engineering, King Abdullah University of Scicence and Technology, Thuwal 23955-6900, Saudi Arabia. E-mail: hkw@kaust.edu.sa

Time:16:00-17:30, December 19, 2014(iChEM meeting)

Location:Room 201, Tong-an Building

Abstract:

A new class of pincer ligands that have a unique disubstituted phosphinoamino (NH-PR2) arm is introduced. Upon complexation to transition metals, a series of ruthenium, rhodium, nickel, iron, chromium, and cobalt complexes have been proven to be efficient catalysts for dehydrogenative coupling, hydrogenation, and olefin polymerization reactions. Selective examples of ethanol dehydrogenation to ethyl acetate and carbon dioxide reduction will be highlighted.

Keywords: Cooperative Catalysis, Dehydrogenation, Hydrogenation, CO2 reduction

Dr. Kuo-Wei Huang’ CV

EDUCATION:

2000-2004

1993-1997

Ph.D.Stanford University

B.S. National Taiwan University

WORKEXPERIENCE:

10.2009-present

10.2007-09.2009

10.2004-09.2007

09.1999-07.2000

01.1998-08.1999

Assistant to AssociateProfessor, Division PhysicalSciences& Engineering, KAUST

Assistant Professor, Department of Chemistry, National University of Singapore

Goldhaber Distinguished Fellow, Brookhaven National Laboratory

Full Time Teaching Assistant, Department of Chemistry, National Taiwan University

Second Lieutenant, Taiwan Military Police Command

 

发布日期:2014/12/01 发布者: 点击数:打印