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Surfactant-free single-layer graphene in water

Dispersing graphite in water to obtain true (single-layer) graphene in bulk quantity in a liquid has been an unreachable goal for materials scientists in the past decade. Similarly, a diagnostic tool to identify solubilized graphene in situ has been long awaited. Here we show that homogeneous stable dispersions of single-layer graphene (SLG) in water can be obtained by mixing graphenide (negatively charged graphene) solutions in tetrahydrofuran with degassed water and evaporating the organic solvent. In situ Raman spectroscopy of these aqueous dispersions shows all the expected characteristics of SLG. Transmission electron and atomic force microscopies on deposits confirm the single-layer character. The resulting additive-free stable water dispersions contain 400 m2 l-1 of developed graphene surface. Films prepared from these dispersions exhibit a conductivity of up to 32 kS m-1.

Nature Chemistry (2016) doi:10.1038/nchem.2669
Received 17 April 2016 Accepted 05 October 2016 Published online 28 November 2016

http://www.nature.com/nchem/journal/vaop/ncurrent/pdf/nchem.2669.pdf

发布日期:2016/12/02 发布者: 点击数: