Size and shape tunability and low-cost solution processability make colloidal lead chalcogenide quantum dots (QDs) an emerging class of building blocks for innovative photovoltaic, thermoelectric and optoelectronic devices. Lead chalcogenide QDs are known to crystallize in the rock-salt structure, although with very different atomic order and stoichiometry in the core and surface regions; however, there exists no convincing prior identification of how extreme downsizing and surface-induced ligand effects influence structural distortion. Using forefront X-ray scattering techniques and density functional theory calculations, here we have identified that, at sizes below 8 nm, PbS and PbSe QDs undergo a lattice distortion with displacement of the Pb sublattice, driven by ligand-induced tensile strain. The resulting permanent electric dipoles may have implications on the oriented attachment of these QDs. Evidence is found for a Pb-deficient core and, in the as-synthesized QDs, for a rhombic dodecahedral shape with nonpolar {110} facets. On varying the nature of the surface ligands, differences in lattice strains are found.

Nature Materials (2016) doi:10.1038/nmat4661
Received 16 June 2015 Accepted 11 May 2016 Published online 13 June 2016

http://www.nature.com/nmat/journal/vaop/ncurrent/full/nmat4661.html

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http://mp.weixin.qq.com/s?__biz=MzA3NjIwODA1Nw==&mid=2650222229&idx=1&sn=c0eb1f08d4c53c3d9e934d4944f348aa&scene=1&srcid=06200XqdfIgnDHSYRhPmAzl8#rd