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Synthesis of Oligoparaphenylene-Derived Nanohoops Employing an Anthracene Photodimerization–Cycloreversion Strategy

The century-old yet synthetically underexplored anthracene photodimerization–cycloreversion reactions have been employed as the key steps to access highly strained aromatic hydrocarbons. Herein we report the chemical syntheses of oligoparaphenylene-derived nanohoops in five steps or less featuring a rigid dianthracene synthon. The newly synthesized nanohoops display intriguing experimental and computational properties.

J. Am. Chem. Soc., 2016, 138 (35), pp 11144–11147
DOI: 10.1021/jacs.6b07673

http://pubs.acs.org/doi/suppl/10.1021/jacs.6b07673

中文报道链接:
http://mp.weixin.qq.com/s?__biz=MzA5NzIyNjEzNQ==&mid=2652816775&idx=7&sn=d2ae8249b37a0137e3578fcf98ad3ed1&scene=1&srcid=09120DweIaMprqECWNoJmfHH#rd

发布日期:2016/09/12 发布者:网站管理员 点击数: