“2011-iChEM讲座”第16讲暨南强学术讲座:Chemistry for Nano, and Nano for Medicine & Energy

报告题目:Chemistry for Nano, and Nano for Medicine & Energy

报 告 人: Taeghwan Hyeon
        Center for Nanoparticle Research, Institute for Basic Science (IBS)
        School of Chemical and Biological Engineering, Seoul National University

时    间: 2018年12月14日(周五)上午10:00

地    点: 厦门大学化学化工学院化学报告厅


Over the last 20 years, our laboratory has focused on the designed chemical synthesis, assembly and applications of uniform-sized nanocrystals. In particular, we developed a novel generalized procedure called as the “heat-up process” for the direct synthesis of uniform-sized nanocrystals of many metals, oxides, and chalcogenides.1 For the last 10 years, our group has been focused on medical applications of various uniform-sized nanoparticles. Very recently, we report that uniform-sized iron oxide nanoclusters can be successfully used as T1 MR contrast agent for high-resolution MR angiography of macaque monkeys.2 We reported the first successful demonstration of high-resolution in vivo three-photon imaging using biocompatible and bright Mn2+ doped ZnS nanocrystals.3

I will present recent advances on the fabrication of stretchable electronic & optoelectronic devices integrated with various functional nanomaterials and their applications to wearable & implantable healthcare devices. We reported graphene-hybrid electrochemical devices integrated with thermo-responsive micro-needles for the sweat-based diabetes monitoring and feedback therapy.4,5 We introduced electromechanical cardioplasty using an epicardial mesh made of electrically conductive and elastic Ag nanowire-rubber composite material to resemble the innate cardiac tissue and confer cardiac conduction system function.6

Recently we have focused on the architecture engineering of nanomaterials for their applications to lithium ion battery, fuel cell electrocatalysts, solar cells, and thermoelectrics. We reported the first demonstration of galvanic replacement reactions in metal oxide nanocrystals, and were able to synthesize hollow nanocrystals of various multimetallic oxides including Mn3O4/γ-Fe2O3.7 We report a simple synthetic method of carbon-based hybrid cellular nanosheets loaded with SnO2 nanoparticles.8 We designed hollow anatase TiO2 nanostructures composed of interconnected ~5 nm-sized nanocrystals, which can individually reach the theoretical lithium storage limit and maintain a stable capacity during prolonged cycling.9 These iron oxide-based nanomaterials exhibited very high specific capacity and good cyclability for lithium ion battery anodes. We present a synthesis of highly durable and active electrocatalysts based on ordered fct-PtFe nanoparticles and FeP nanoparticles coated with N-doped carbon shell.10,11

1. "Ultra-Large Scale Syntheses of Monodisperse Nanocrystals," Nature Mater. 2004, 3, 891.

2. “Iron oxide nanoclusters for T1 MRI of nonhuman primates,” Nature Biomed. Eng. 2017, 1, 637.

3. “High-Resolution Three-Photon Biomedical Imaging using Doped ZnS Nanocrystals,” Nature Mater. 2013, 12, 359.

4. “A graphene-based electrochemical device with thermo-responsive microneedles for diabetes monitoring and therapy,” Nature Nanotech. 2016, 11, 566.

5. “Wearable/disposable sweat-based glucose monitoring device with multi-stage transdermal drug delivery module,” Science Adv. 2017, 3, e1601314.

6. “Electromechanical cardioplasty using a wrapped elasto-conductive epicardial mesh,” Science Transl. Med. 2016, 8, 344ra86; “Highly conductive, stretchable, and biocompatible Ag-Au core-sheath nanowire composite for wearable and implantable bioelectronics,” Nature Nanotech. 2018, in press.

7. “Galvanic Replacement Reactions in Metal Oxide Nanocrystals,” Science 2013, 340, 964.

8. “Hybrid Cellular Nanosheets for High-Performance Lithium Ion Battery Anodes,” J. Am. Chem. Soc. 2015, 137, 11954.

9. “Engineering Titanium Dioxide Nanostructures for Enhanced Lithium-Ion Storage,” J. Am. Chem. Soc., 2018, 140, in press.

10. “Highly durable and active PtFe nanocatalyst for electrochemical oxygen reduction reaction,” J. Am. Chem. Soc. 2015, 137, 15478.

11. “Large-scale Synthesis of Carbon Shell-coated FeP Nanoparticles for Robust Hydrogen Evolution Reaction Electrocatalyst,” J. Am. Chem. Soc. 2017, 139, 6669.


Prof. Taeghwan Hyeon(玄泽焕教授)是韩国首尔国立大学教授。美国材料学会院士,英国皇家化学会院士,韩国科学翰林院院士,韩国工程院院士。现担任国际顶尖化学期刊J. Am. Chem. Soc. (JACS)副主编,同时担任Advanced Materials, Nano Today, ACS Central Science等8个国际顶尖材料、化学期刊的编委。玄泽焕教授是纳米科技领域的国际顶尖专家和领军人物之一,开创了绿色和大量合成均一尺寸纳米粒子的新方法,领导了纳米材料在医学成像和治疗领域的应用,在Science, Nature Mater., Nature Nanotechnol., Nature Comm., J. Am. Chem. Soc., Angew. Chem. 等国际顶级期刊发表论文350余篇,论文总被引次数超过42000次,h-index大于110。入选UNESCO&IUPAC评选的国际顶尖100化学家和材料学家(化学领域世界第37名,材料领域世界第19名)。



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